LiFePO4 Lithium Iron Phosphate battery basics

These days, 12 volt, 24V, and 48V energy storage systems tend to consist of batteries with the LiFePO4 (Lithium Iron Phosphate) chemistry.

Warning, don’t confuse LiFePO4 batteries with other Li ion (lithium ion) and Li-po (lithium polymer) batteries. Their maximum voltage and charging/discharging characteristics are different.

Some people abbreviate LiFePO4 even further to LFP.

Almost all batteries are made up of cells connected in series to add up to the desired voltage, and often in parallel to increase capacity. The voltages involved with LifePO4 batteries are very similar to those of 12V, 24V etc. lead acid batteries. Therefore with some precautions, LiFePO4 usually replace lead acid batteries in systems made for lead acid.

  • 3.2V to 3.65V is the typical voltage range of a LiFePO4 cell.
  • 4 series cell will have a typical voltage range of 12.8V to  14.6V. 4 series cells is how most batteries come unless you want to build your own battery from individual cells.
  • When the charging voltage is removed, the charged voltage will quickly settle to about 3.4V per cell or 13.6V for 4 series cells.
  • Higher voltage than 3.65V per cell/14.6V per 4 series cells, may damage the cell or battery.
  • Lower voltage than 2.5V per cell/10V per 4 series cells, may damage the battery.
  • Not to be charged when they are cold. Especially below freezing (oC, 32F).
  • Absorption (time): Temporarily raising the voltage of the cells higher than the max voltage that they provide power at once fully charged. Gets the most charge into the battery. Balances the cells.
  • Float: LiFePO4 doesn’t need float, but many chargers that also charge lead acid batteries will have a float setting. It is a voltage that the charger will hold the battery to after the battery was considered fully charged. LiFePO4 batteries hold their fully charged voltage for a long time. You can set the float voltage to that voltage. Lead acid does not hold it’s voltage and charge over time, so a charger will keep it toped off.

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Charging cycle:

  • Bulk: Constant current phase.
  • Absorption: Constant voltage.
  • Topping charge: A charger might recharge an already charged battery whose charge went down over a period of time after it was charged. LiFePO4 hold their charge for a long time, so, this is not common.
  • Float: Optional
  • Equalization: Optional. (finish charging a battery that didn’t go through the full Bulk, absorption and Float charging cycle.
  • C rate. 1C charging or discharging, means that the battery is getting or giving the amount of current that it is rated for in Amp hours. Commonly recommended to charge LiFePO4 batteries at 0.2C. So, a 10Ah LiFePO4 battery would be charging at 1C if it was being given 10A of current, which is really high. So, it’d be better to charge a 10Ah LiFePO4 battery at 2A (0.2C). 0.2C for a 4Ah battery would be 7Ah x 0.2C = 1.4A.
  • Sleeping LiFoPO4 battery. BMS totally disconnects from the battery because it is too discharged. BMS must be woken up and battery must be recharged.

Other topics:

  • BMS is circuitry added to the battery to monitor battery parameters and take certain actions to protect it. It’s generally built into prebuilt batteries by the battery manufacturer.
  • BMS from different brands/models might not get along together. It’s sometimes best to series/parallel only the exact same batteries, and as the manufacturer recommends.

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